It could definitely sting through its own exoskeleton.
That being said, this myth, in its various forms, is just that -- a myth. There is one that if you surround a scorpion by fire it will sting itself to death rather than be burned. Anyhow, it is all nonsense.
I started to go through that whole site. I was going to comment on all the ones I knew to be false, but about half of them are like that and the other half are suspect but I don't know for sure one way or the other. There are only a couple that actually sound plausable to me.
Cheers,
Dave
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