Re: Bioactive?? Or, no?
I wouldn't worry about doing a "true" bioactive with a kingsnake. Kingsnakes burrow and they'll mess up the layering system in a bioactive setup.
You can use a mixture of reptichip and coconut coir/eco earth for the substrate. That'll be adequate to support a pothos plant, which should be sturdy enough to survive the snake's burrowing.
Bringing a couple handfuls of clean, pesticide free oak or maple leaves will seed the tank with springtails or similar invertebrates to act as a clean-up crew. Depending on your location, later this spring or summer you should also be able to find some isopods/roly polies to add as well.
If you don't mind finding the occasional dried up worm in your house then you can add some red wrigglers (fishing bait worms) to the tank as well. (I personally do not recommend adding the worms.)
I have a Japanese rat snake in an enclosure with the substrate and plants I listed above. He seems to be doing very well in there and the plants are hanging in there so far. My corn snake managed to kill its pothos plants.
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