They don't hiss because they are hungry, they hiss as part of a defense mechanism. Something is upsetting your snake, and many things can cause that type of behaviour. It can be something as simple as your snake is going to shed soon and its senses are down, it can be stressed out from an inadequate environment, illness, too much exposure, or even something such as it is a baby that is naturally defensive as it has not yet become accustomed to people or its surroundings. Sometimes snakes even seem to just have 'bad days'.
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